Chapter 1 The reaction heat

Chapter 1 The reaction heat

1、单选题:
‏Which term is not the state function?  ​
选项:
A: enthalpy
B: internal energy
C: heat
D: mass
答案: 【 heat

2、单选题:
‍Which term is not the state function?  ‌
选项:
A: work
B: volume
C: entropy
D: Gibbs free energy
答案: 【 work

3、单选题:
​Which  processe is exothermic?‎
选项:
A: boil water
B: melt ice
C: evaporate water
D: freeze water
答案: 【 freeze water

4、单选题:
‏Which  processes is endothermic?‏
选项:
A: C(s) + O2(g)=CO2(g)
B: 2H2(g) + O2(g)=2H2O(l)
C: 2NH3(g)=3H2(g) + N2(g)
D: 2C(s) + O2(g)=2CO(g)
答案: 【 2NH3(g)=3H2(g) + N2(g)

5、单选题:
‏For a system, suppose it adsorb 100 kJ of heat from the surroundings and do 50 kJ of work to the surroundings, how much is its internal energy change?    ‍
选项:
A: +150kJ 
B:  -150 kJ
C: 50 kJ 
D: -50 kJ
答案: 【 50 kJ 

6、单选题:
‏Which  standard molar enthopy of formation  is zero?​
选项:
A: CO2
B: C (diamond) 
C: NH3 
D: O2
答案: 【 O2

7、单选题:
‍In the following reactions, which ΔrHmΘ is equal to the ΔfHmΘ? ‏
选项:
A: 1/2N2 (g)  +  3/2H2(g)  =  NH3(g)
B:  CaCO3(s) = CaO(s) + CO2(g)
C: NaOH (aq) + HCl(aq) = NaCl(aq) + H2O(l)
D: CO(g) + 1/2O2(g) = CO2(g)
答案: 【 1/2N2 (g)  +  3/2H2(g)  =  NH3(g)

8、单选题:
Which item is equal to the reaction heat in the constant volume process of closed system?‍‎‍
选项:
A: ∆S
B: -PV
C: ∆U
D: ∆G
答案: 【 ∆U

9、单选题:
Which item is equal to the enthalpy?‍‌‍
选项:
A: U+PV
B: U-PV
C:  U-TV 
D: U+TV
答案: 【 U+PV

10、单选题:
For the reaction, CO(g)+1/2O2(g)=CO2(g) ∆H= -280.0 kJ/mol and C(s)+O2(g)=CO2(g) ∆H= -393.5 kJ/mol, how much is the reaction heat of C(s)+1/2O2(g)=CO(g)?‌​‌
选项:
A: 113.5 kJ/mol
B: -113.5 kJ/mol
C: -673.5 kJ/mol
D: 673.5 kJ/mol
答案: 【 -113.5 kJ/mol

11、单选题:
For a reaction, if it releases 398 kJ/mol of heat in the forward process, how much is the heat of its reverse process?‎‍‎
选项:
A: 398 kJ/mol
B: -398 kJ/mol
C:  0 kJ/mol
D: unknown
答案: 【 398 kJ/mol

12、单选题:
‎In which case the reaction heat is equal to the enthalpy change?‏
选项:
A: The process of constant pressure for a closed system
B: The process of constant volume for a closed system
C: The process of constant pressure for an opened system
D: The process of constant volume for an opened system
答案: 【 The process of constant pressure for a closed system

13、判断题:
‍Under standard state,the enthalpy change of △rHmΘ for the reaction C(graphite) + O2(g) =CO2(g) is equal to the △fHmΘ of CO­2.  ‏
选项:
A: 正确
B: 错误
答案: 【 正确

14、判断题:
‍The change of work in any process can be calculated by ΔW=W2-W1‍
选项:
A: 正确
B: 错误
答案: 【 错误

15、判断题:
​The following item of △H, H, S and T are all state function.‏
选项:
A: 正确
B: 错误
答案: 【 错误

16、判断题:
‏According to the Hess law, the reaction heat is state function.‏
选项:
A: 正确
B: 错误
答案: 【 错误

17、判断题:
‎The internal energy of a system is state function.‏
选项:
A: 正确
B: 错误
答案: 【 正确

Chapter 2 The direction and equilibrium of reaction

Chapter 2 The direction and equilibrium of reaction

1、单选题:
‌Which substance has the biggest entropy?‎
选项:
A: H2O(l)
B: NaCl (s)
C: N2 (g) 
D: CaCO3(s)
答案: 【 N2 (g) 

2、单选题:
‌Which value is zero at standard state?‏
选项:
A: SmΘ (standard entropy)
B: GmΘ (standard Gibbs free energy)
C: ΔfHmΘ (standard enthalpy of formation)
D: UmΘ (internal energy)
答案: 【 ΔfHmΘ (standard enthalpy of formation)

3、单选题:
‎Which entropy change  is positive?​
选项:
A: O2(g)+2H2(g)=2H2O(g)
B: CaCO3(s)=CaO(s)+CO2(g)
C: N2(g)+3H2(g)=2NH3(g)
D: 2Mg(s)+O2(g)=2MgO(s)
答案: 【 CaCO3(s)=CaO(s)+CO2(g)

4、单选题:
‌Which  reaction is spontaneous under the standard state?‍
选项:
A: 1/2N2 (g)  +  3/2H2(g)  =  NH3(g)   ΔrGmΘ= -16.5kJ/mol
B: CaCO3(s) = CaO(s) + CO2(g) ΔrGmΘ=130.4kJ/mol
C: H2O(l) = H2(g) +1/2O2(g) ΔrGmΘ=237.2kJ/mol
D: CO2(g) = C(s) + O2(g)     ΔrGmΘ=394.4kJ/mol
答案: 【 1/2N2 (g)  +  3/2H2(g)  =  NH3(g)   ΔrGmΘ= -16.5kJ/mol

5、单选题:
‍Which case is favored for  the reaction occurred spontaneouly  with temperature increasing?  ‏
选项:
A: ΔrHmΘ>0, ΔrSmΘ<0 
B:  ΔrHmΘ>0, ΔrSmΘ>0
C: ΔrHmΘ<0, ΔrSmΘ<0
D: uncertain
答案: 【  ΔrHmΘ>0, ΔrSmΘ>0

6、单选题:
​Which function is affected by the temperature  obviously?‌
选项:
A: ΔrHmΘ
B: ΔrSmΘ
C: ΔrGmΘ
D: QP
答案: 【 ΔrGmΘ

7、单选题:
​For the reaction 2SO3(g)=2SO2(g)+O2(g), it’s KpΘ is 32,if the equilibrium concentration of [SO3]=[O2]=2.0mol·L-1 , how much is the equilibrium concentration of  SO2? ‌
选项:
A:  0.032 mol·L-1 
B: 8.0 mol·L-1 
C: 0.25 mol·L-1
D: 2.7 mol·L-1 
答案: 【 8.0 mol·L-1 

8、单选题:
‏Increase the volume of the system 2SO3(g)=2SO2(g)+O2(g), which side will the reaction move to?‌‏‌
选项:
A: left
B: right
C: uncertain
D: not move
答案: 【 right

9、单选题:
‌For the exothermic reaction 2C(graphite) +O2(g) =2CO(g), which side will it move to with increasing the temperature?‌‌‌
选项:
A: left
B: right
C: uncertain
D: not move
答案: 【 left

10、判断题:
​The △rS mΘ of the reaction 2NO(g)+O2(g) =2NO2(g)  is negative.‎
选项:
A: 正确
B: 错误
答案: 【 正确

11、判断题:
‎All these items  H, S, G, △H, △S and △G are varied with temperature. ‏
选项:
A: 正确
B: 错误
答案: 【 错误

12、判断题:
‏If△GΘ> 0, the reaction can’t occur spontaneously at any condition.‌
选项:
A: 正确
B: 错误
答案: 【 错误

13、判断题:
​For any reaction, the equilibrium constant KΘ will increase with temperature increasing.‍
选项:
A: 正确
B: 错误
答案: 【 错误

14、判断题:
​For the reaction 2C(graphite) +O2(g) =2CO(g), △rSmΘ is positive. ‍
选项:
A: 正确
B: 错误
答案: 【 正确

15、判断题:
Decrease temperature is favored for the reaction N2(g) +H2(g)=NH3(g) to produce ammonia.‍‎‍
选项:
A: 正确
B: 错误
答案: 【 错误

Chapter 3 The Rates of Chemical Reactions

剩余75%内容付费后可查看

发表评论

电子邮件地址不会被公开。 必填项已用*标注